Issue 2, 2016
From the journal:

Organic & Biomolecular Chemistry

On the association of neutral and cationic tris(tetrathiafulvaleno)dodecadehydro[18]annulenes†

Christian R. Parker,a   Kasper Lincke,ab   Mikkel A. Christensen,a   Karol Lušpai,c   Peter Rapta,c   Thomas Just Sørensen,a   Thorbjørn J. Morsing,a   Lin Du,a   Henrik G. Kjaergaard,a   Ole Hammerich,a   François Diederichb  and  Mogens Brøndsted Nielsen*a  

* Corresponding authors

a Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark
E-mail: mbn@chem.ku.dk

b Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, Wolfgang-Pauli-Strasse 10, CH-8093 Zürich, Switzerland

c Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinskeho 9, SK-81237 Bratislava, Slovak Republic

Abstract

Here, we report the first X-ray crystal structure of a tetrathiafulvalene-fused dehydroannulene with peripheral ethylthio substituents. In addition, we have subjected this compound to electrochemical and UV-Vis-NIR/ESR spectroelectrochemical studies to elucidate the degree to which the oxidised species associate.

Graphical abstract: On the association of neutral and cationic tris(tetrathiafulvaleno)dodecadehydro[18]annulenes

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Article information

DOI
https://doi.org/10.1039/C5OB02087E
Article type
Communication
Submitted
08 Oct 2015
Accepted
03 Nov 2015
First published
03 Nov 2015

Org. Biomol. Chem., 2016,14, 425-429

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On the association of neutral and cationic tris(tetrathiafulvaleno)dodecadehydro[18]annulenes

C. R. Parker, K. Lincke, M. A. Christensen, K. Lušpai, P. Rapta, T. J. Sørensen, T. J. Morsing, L. Du, H. G. Kjaergaard, O. Hammerich, F. Diederich and M. B. Nielsen, Org. Biomol. Chem., 2016, 14, 425 DOI: 10.1039/C5OB02087E

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