Issue 7, 2016
From the journal:

Chemical Communications

NHPI and palladium cocatalyzed aerobic oxidative acylation of arenes through a radical process†

Yu-Feng Liang,a   Xiaoyang Wang,a   Conghui Tang,a   Tao Shen,a   Jianzhong Liua  and  Ning Jiao*ab  

* Corresponding authors

a State Key Laboratory of Natural and Biomimetic Drugs, Peking University, School of Pharmaceutical Sciences, Peking University, Xue Yuan Rd. 38, Beijing 100191, China
E-mail: jiaoning@pku.edu.cn
Fax: +86-010-8280-5297

b State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

The NHPI and palladium cocatalyzed radical oxidative acylation of arenes with aldehydes and alcohols as acyl equivalents via selective C–H functionalization has been described. Molecular oxygen, the most environmentally friendly oxidant, was used as the terminal oxidant in this catalytic cycle.

Graphical abstract: NHPI and palladium cocatalyzed aerobic oxidative acylation of arenes through a radical process

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Article information

DOI
https://doi.org/10.1039/C5CC08945J
Article type
Communication
Submitted
28 Oct 2015
Accepted
19 Nov 2015
First published
19 Nov 2015

Chem. Commun., 2016,52, 1416-1419

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NHPI and palladium cocatalyzed aerobic oxidative acylation of arenes through a radical process

Y. Liang, X. Wang, C. Tang, T. Shen, J. Liu and N. Jiao, Chem. Commun., 2016, 52, 1416 DOI: 10.1039/C5CC08945J

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