Issue 12, 2016
From the journal:

Chemical Communications

CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligands†

Farhan Ahmad Pasha,‡a   Anissa Bendjeriou-Sedjerari,‡a   Edy Abou-Hamad,a   Kuo-Wei Huanga  and  Jean-Marie Basset*a  

* Corresponding authors

a King Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC), Thuwal, Saudi Arabia
E-mail: jeanmarie.basset@kaust.edu.sa

Abstract

Density functional theory calculations and 2D 1H–13C HETCOR solid state NMR spectroscopy prove that CO2 can be used to probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [([triple bond, length as m-dash]Si–O–)([triple bond, length as m-dash]Si–N[double bond, length as m-dash])[Zr]H] and [([triple bond, length as m-dash]Si–NH–)([triple bond, length as m-dash]Si–X–)[Zr]H2] (X[double bond, length as m-dash]O or NH). Moreover, [([triple bond, length as m-dash]Si–O–)([triple bond, length as m-dash]Si–N[double bond, length as m-dash])[Zr]H] activates CO2 more efficiently than the other complexes and leads to the formation of a carbimato Zr formate.

Graphical abstract: CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligands

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Article information

DOI
https://doi.org/10.1039/C5CC08821F
Article type
Communication
Submitted
26 Oct 2015
Accepted
01 Jan 2016
First published
04 Jan 2016

Chem. Commun., 2016,52, 2577-2580

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CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligands

F. A. Pasha, A. Bendjeriou-Sedjerari, E. Abou-Hamad, K. Huang and J. Basset, Chem. Commun., 2016, 52, 2577 DOI: 10.1039/C5CC08821F

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