Issue 73, 2015
From the journal:

Chemical Communications

Stereoselective synthesis of vinylphosphonates and phosphine oxides via silver-catalyzed phosphorylation of styrenes†

Qingwen Gui,a   Liang Hu,a   Xiang Chen,a   Jidan Liua  and  Ze Tan*a  

* Corresponding authors

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China
E-mail: ztanze@gmail.com

Abstract

An efficient and stereoselective synthesis of vinylphosphonates and phosphine oxides was developed starting from styrenes using AgNO3 as the catalyst and K2S2O8 as the oxidant. The success of the reaction was found to be critically dependent on the use of TEMPO as the additive.

Graphical abstract: Stereoselective synthesis of vinylphosphonates and phosphine oxides via silver-catalyzed phosphorylation of styrenes

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Article information

DOI
https://doi.org/10.1039/C5CC04826E
Article type
Communication
Submitted
11 Jun 2015
Accepted
22 Jul 2015
First published
28 Jul 2015

Chem. Commun., 2015,51, 13922-13924

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Stereoselective synthesis of vinylphosphonates and phosphine oxides via silver-catalyzed phosphorylation of styrenes

Q. Gui, L. Hu, X. Chen, J. Liu and Z. Tan, Chem. Commun., 2015, 51, 13922 DOI: 10.1039/C5CC04826E

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