Issue 72, 2015
From the journal:

Chemical Communications

A neutral low-coordinate heterocyclic bismuth-tin species†

C. Hering-Junghans,a   A. Schulz*ab  and  A. Villingera  

* Corresponding authors

a Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany
E-mail: axel.schulz@uni-rostock.de

b Abteilung Materialdesign, Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany

Abstract

The reaction of distannadiazane bearing bulky RAr*-groups (RAr* = C6H2{C(H)Ph2}2R-2,6,4; R = iPr, tBu) with ECl3 (E = Sb, Bi) was studied resulting in the isolation of previously unknown N,N-bis(dichloropnictino)amines (3) and a novel heterocyclic carbenoid bismuth species (4) bearing a Bi(III) and a Sn(IV) center. The structure and bonding was investigated by means of X-ray structure elucidations and DFT calculations.

Graphical abstract: A neutral low-coordinate heterocyclic bismuth-tin species

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC04516A
Article type
Communication
Submitted
02 Jun 2015
Accepted
22 Jul 2015
First published
23 Jul 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 13834-13837

Author version available

Download author version (PDF)

Permissions

Request permissions

A neutral low-coordinate heterocyclic bismuth-tin species

C. Hering-Junghans, A. Schulz and A. Villinger, Chem. Commun., 2015, 51, 13834 DOI: 10.1039/C5CC04516A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements