Issue 52, 2015

One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation

Abstract

The hydrogenation efficiency of nitro compounds was found to be greatly boosted by coupling with dehydrogenation of ammonia borane. The Pd@MIL-101 with tiny Pd NPs is exceptionally efficient and recyclable in the tandem reactions and diverse nitro compounds can be selectively reduced to the corresponding amines in 1.5–5 min with quantitative yields.

Graphical abstract: One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation

Supplementary files

Article information

Article type
Communication
Submitted
15 Apr 2015
Accepted
11 May 2015
First published
11 May 2015

Chem. Commun., 2015,51, 10419-10422

Author version available

One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation

Q. Yang, Y. Chen, Z. U. Wang, Q. Xu and H. Jiang, Chem. Commun., 2015, 51, 10419 DOI: 10.1039/C5CC03102H

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