Issue 35, 2015
From the journal:

Chemical Communications

In situ encapsulation of Pd inside the MCM-41 channel†

Xi-Jie Lin,ab   Ai-Zhi Zhong,ab   Yong-Bin Sun,b   Xing Zhang,b   Wei-Guo Song,b   Rong-Wen Lu,*a   An-Min Cao*b  and  Li-Jun Wan*b  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, P. R. China
E-mail: lurw@dlut.edu.cn

b Key Laboratory of Molecular Nanostructure and Nanotechnology and Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, P. R. China
E-mail: anmin_cao@iccas.ac.cn, wanlijun@iccas.ac.cn

Abstract

Pd nanoparticles were successfully introduced into the channels of mesoporous silica MCM-41 with their dispersion well-tuned. We identified the dual role played by CTAB, which was critical for both the micelle template and Pd grafting, leading to the formation of a highly active Pd–MCM-41 nanocomposite for catalysing the Suzuki reaction.

Graphical abstract: In situ encapsulation of Pd inside the MCM-41 channel

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Article information

DOI
https://doi.org/10.1039/C5CC00300H
Article type
Communication
Submitted
13 Jan 2015
Accepted
23 Mar 2015
First published
24 Mar 2015

Chem. Commun., 2015,51, 7482-7485

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In situ encapsulation of Pd inside the MCM-41 channel

X. Lin, A. Zhong, Y. Sun, X. Zhang, W. Song, R. Lu, A. Cao and L. Wan, Chem. Commun., 2015, 51, 7482 DOI: 10.1039/C5CC00300H

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