Issue 34, 2014

Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

Abstract

A facile Zn-induced reductive homocoupling reaction was used to synthesize azo-linked porous organic frameworks (azo-POFs) from easily accessed nitro monomers. Azo-POF-2 exhibits the highest CO2/N2 selectivity of 76 at 273 K among all self-coupled azo-linked porous polymers.

Graphical abstract: Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

Supplementary files

Article information

Article type
Communication
Submitted
14 Jun 2014
Accepted
26 Jun 2014
First published
02 Jul 2014

J. Mater. Chem. A, 2014,2, 13831-13834

Author version available

Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

J. Lu and J. Zhang, J. Mater. Chem. A, 2014, 2, 13831 DOI: 10.1039/C4TA03015J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements