Room temperature Suzuki coupling of aryl iodides, bromides, and chlorides using a heterogeneous carbon nanotube-palladium nanohybrid catalyst

Dhanaji V. Jawale; Edmond Gravel; Caroline Boudet; Nimesh Shah; Valérie Geertsen; Haiyan Li; Irishi N. N. Namboothiri; Eric Doris

doi:10.1039/C4CY01680G

Room temperature Suzuki coupling of aryl iodides, bromides, and chlorides using a heterogeneous carbon nanotube-palladium nanohybrid catalyst†

Dhanaji V. Jawale,^a Edmond Gravel,^a Caroline Boudet,^a Nimesh Shah,^b Valérie Geertsen,^c Haiyan Li,^d Irishi N. N. Namboothiri*^b and Eric Doris*^a

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* Corresponding authors

^a CEA, iBiTecS, Service de Chimie Bioorganique et de Marquage, 91191 Gif-sur-Yvette, France
E-mail: eric.doris@cea.fr

^b Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400 076, India
E-mail: irishi@chem.iitb.ac.in

^c CEA, IRAMIS, Nanosciences et Innovation pour les Matériaux, la Biomédecine et l'Energie, UMR3299, 91191 Gif-sur-Yvette, France

^d State Key Laboratory of Physical Chemistry for Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers, and Esters, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Abstract

Palladium nanoparticles were immobilized on multi-walled carbon nanotubes by a layer-by-layer approach, resulting in a well-defined assembly. The nanohybrid was found effective in promoting Suzuki cross couplings of various halogenated aromatics, including chlorinated ones, with arylboronic acids under sustainable conditions. The heterogeneous catalyst could also easily be recovered from the reaction mixture and reused with no loss of activity over several cycles.

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DOI: https://doi.org/10.1039/C4CY01680G
Article type: Paper
Submitted: 16 Dec 2014
Accepted: 29 Jan 2015
First published: 29 Jan 2015
This article is Open Access

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Catal. Sci. Technol., 2015,5, 2388-2392

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Room temperature Suzuki coupling of aryl iodides, bromides, and chlorides using a heterogeneous carbon nanotube-palladium nanohybrid catalyst

D. V. Jawale, E. Gravel, C. Boudet, N. Shah, V. Geertsen, H. Li, I. N. N. Namboothiri and E. Doris, Catal. Sci. Technol., 2015, 5, 2388 DOI: 10.1039/C4CY01680G

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Catalysis Science & Technology

Room temperature Suzuki coupling of aryl iodides, bromides, and chlorides using a heterogeneous carbon nanotube-palladium nanohybrid catalyst†

Abstract

Supplementary files

Article information

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Room temperature Suzuki coupling of aryl iodides, bromides, and chlorides using a heterogeneous carbon nanotube-palladium nanohybrid catalyst

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