Issue 12, 2015

Post metalation of solvothermally grown electroactive porphyrin metal–organic framework thin films

Abstract

Uniform thin films of a metal–organic framework, which is constructed from free-base porphyrin linkers and hexa-zirconium nodes (MOF-525), are solvothermally grown on conducting substrates. Subsequently, solvothermal post metalations are employed to prepare the Zn-MOF-525 and Co-MOF-525 thin films. All the thin films are electroactive in aqueous media.

Graphical abstract: Post metalation of solvothermally grown electroactive porphyrin metal–organic framework thin films

Supplementary files

Article information

Article type
Communication
Submitted
20 Nov 2014
Accepted
23 Dec 2014
First published
24 Dec 2014

Chem. Commun., 2015,51, 2414-2417

Post metalation of solvothermally grown electroactive porphyrin metal–organic framework thin films

C. Kung, T. Chang, L. Chou, J. T. Hupp, O. K. Farha and K. Ho, Chem. Commun., 2015, 51, 2414 DOI: 10.1039/C4CC09272D

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