Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation

Koroush Sasan; Qipu Lin; ChengYu Mao; Pingyun Feng

doi:10.1039/C4CC03946G

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Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation†

Koroush Sasan,^a Qipu Lin,^a ChengYu Mao^b and Pingyun Feng*^ab

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* Corresponding authors

^a Department of Chemistry, University of California, Riverside, California CA 92521, USA

^b Materials Science and Engineering Program, University of California Riverside, CA 92521, USA
E-mail: pingyun.feng@ucr.edu
Fax: +1 951-827-4713
Tel: +1 951-827-2042

Abstract

A new biomimetic heterogeneous photocatalyst ([FeFe]@ZrPF) has been synthesized through the incorporation of homogeneous complex 1 [(í-SCH₂)₂NC(O)C₅H₄N]–[Fe₂(CO)₆] into the highly robust zirconium-porphyrin based metal–organic framework (ZrPF). The immobilized biomimetic [Fe₂S₂] catalyst inside the MOF shows great improvement in hydrogen generation compared to the reference homogeneous catalyst complex 1.

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Article information

DOI: https://doi.org/10.1039/C4CC03946G
Article type: Communication
Submitted: 23 May 2014
Accepted: 25 Jun 2014
First published: 25 Jul 2014

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Chem. Commun., 2014,50, 10390-10393

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Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation

K. Sasan, Q. Lin, C. Mao and P. Feng, Chem. Commun., 2014, 50, 10390 DOI: 10.1039/C4CC03946G

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Chemical Communications

Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation†

Abstract

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Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation

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