Issue 12, 2013

Printable fabrication of Pt-and-ITO free counter electrodes for completely flexible quasi-solid dye-sensitized solar cells

Abstract

Low-cost bendable photoanodes and counter electrodes (CEs), as well as gel electrolytes, are potentially desired for the mass production of completely flexible dye-sensitized solar cells (DSSCs). In this work, via printing at low temperature, we fabricated titanium carbide (TiC)-functionalized conductive-carbon (CC) on flexible polyimide (PI) films to replace traditional and expensive Pt/ITO/PEN CEs. Morphology characterization revealed this composite CE was highly porous and homogeneous. Electrochemical investigations demonstrated that this Pt-and-ITO free flexible CE exhibited a high electro-catalytic activity. Finally, the conversion efficiencies of the all flexible quasi-solid DSSCs using this low-cost TiC-CC/PI CE achieved 86% of that based on a Pt/CC/PI CE. Thus, the facile fabrication process of this novel CE, along with its notable performance, are quite promising for the future roll-to-roll production of completely flexible DSSCs.

Graphical abstract: Printable fabrication of Pt-and-ITO free counter electrodes for completely flexible quasi-solid dye-sensitized solar cells

Article information

Article type
Paper
Submitted
03 Nov 2012
Accepted
10 Jan 2013
First published
07 Feb 2013

J. Mater. Chem. A, 2013,1, 3932-3937

Printable fabrication of Pt-and-ITO free counter electrodes for completely flexible quasi-solid dye-sensitized solar cells

H. Zhou, Y. Shi, D. Qin, J. An, L. Chu, C. Wang, Y. Wang, W. Guo, L. Wang and T. Ma, J. Mater. Chem. A, 2013, 1, 3932 DOI: 10.1039/C3TA00960B

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