Issue 26, 2013

Structural changes within the alkaline earth uranyl phosphites

Abstract

Three new alkaline earth (AE) uranyl phosphites and one barium uranium(IV) phosphate were synthesized under hydrothermal conditions. The carbonate salts of the AE's were employed both as cation sources and as pH regulators. Despite having very similar formulas and uranyl building units, the Ca2+, Sr2+ and Ba2+ uranyl phosphites have three different extended networks. The calcium compound also contains a Ca2+/UO22+ mixed cation position. The four structure types will be presented herein with the AE cations generating distinct structural transformations.

Graphical abstract: Structural changes within the alkaline earth uranyl phosphites

Supplementary files

Article information

Article type
Paper
Submitted
21 Mar 2013
Accepted
02 May 2013
First published
15 May 2013

Dalton Trans., 2013,42, 9637-9644

Structural changes within the alkaline earth uranyl phosphites

E. M. Villa, J. Diwu, E. V. Alekseev, W. Depmeier and T. E. Albrecht-Schmitt, Dalton Trans., 2013, 42, 9637 DOI: 10.1039/C3DT50769F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements