Issue 22, 2013
From the journal:

Dalton Transactions

Sequential growth of bistable copper–molybdenum coordination nanolayers on inorganic surfaces†

Simon Tricard,*ab   Yousuf Raza,a   Sandra Mazerat,a   Karim Aissou,c   Thierry Baronc  and  Talal Mallah*a  

* Corresponding authors

a Institut de Chimie Moléculaire et des Matériaux d'Orsay, UMR CNRS 8182, Université Paris-Sud, 91405 Orsay, France
E-mail: simon.tricard@insa-toulouse.fr, talal.mallah@u-psud.fr

b Laboratoire de Chimie de Coordination, UPR CNRS 8241, Université de Toulouse, 31077 Toulouse, France

c Laboratoire des Technologies de la Microélectronique, UMR CNRS 5129, CEA/LETI/D2NT, 38054 Grenoble, France

Abstract

Sequential growth in solution is a powerful tool to control the growth of coordination networks on surfaces. We used this approach to prepare nanolayers of the bistable copper–molybdenum cyanide-bridged network. The nanolayers were grown on functionalized silicon and on bare platinum surfaces. The use of platinum dots organized on silicon oxide led to the growth of isolated and organized coordination objects. The bistable properties, characteristic of the bulk, have been evidenced for the nanolayers using infrared spectroscopy.

Graphical abstract: Sequential growth of bistable copper–molybdenum coordination nanolayers on inorganic surfaces

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Article information

DOI
https://doi.org/10.1039/C3DT50259G
Article type
Paper
Submitted
24 Jan 2013
Accepted
07 Mar 2013
First published
08 Mar 2013

Dalton Trans., 2013,42, 8034-8040

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Sequential growth of bistable copper–molybdenum coordination nanolayers on inorganic surfaces

S. Tricard, Y. Raza, S. Mazerat, K. Aissou, T. Baron and T. Mallah, Dalton Trans., 2013, 42, 8034 DOI: 10.1039/C3DT50259G

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