SCHEDULED MAINTENANCE
Ring opening of 3-oxo-1,2-cyclopropanated sugars with thiols leads to the serendipitous discovery of the synthesis of sugar based homologated acyclic dithioacetals. These acyclic dithioacetals were found to undergo one-pot septanoside formation followed by stereoselective glycosylation in the presence of glycosyl acceptors under glycosylation reaction conditions.
P. Venukumar, C. Sudharani and P. R. Sridhar, Chem. Commun., 2014, 50, 2218 DOI: 10.1039/C3CC49116A
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