SCHEDULED MAINTENANCE
Reaction of the ethyl-aromatic phosphine 1 with PhRh(PPh3)3 results in C–H activation, yielding complex 2, which upon treatment with H2 undergoes selective cleavage of the sp2–sp3 hybridized C–C bond forming ethane and complex 3; Ar–C cleavage is also observed upon reaction of 1 with H2 and [RhCl(C8H14)2]2.
S. Liou, M. Gozin and D. Milstein, J. Chem. Soc., Chem. Commun., 1995, 1965 DOI: 10.1039/C39950001965
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