Issue 17, 1995

The synthesis and structure of {[PimPri,But]ZnOH}(ClO4): a tris(imidazolyl)phosphine zinc hydroxide complex and a proposed structural model for carbonic anhydrase

Abstract

The zinc hydroxide complex {[Pimpri,But]ZnOH}(ClO4) is synthesized by the reaction of [Pimpri,But] with Zn(ClO4)2·6H2O; {[Pimpri,But]ZnOH}(ClO4) is the first structurally characterized monomeric zinc hydroxide complex supported by imidazole functionalities and is therefore an excellent structural model for the active site of carbonic anhydrase.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1813-1815

The synthesis and structure of {[PimPri,But]ZnOH}(ClO4): a tris(imidazolyl)phosphine zinc hydroxide complex and a proposed structural model for carbonic anhydrase

C. Kimblin, W. E. Allen and G. Parkin, J. Chem. Soc., Chem. Commun., 1995, 1813 DOI: 10.1039/C39950001813

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