The germylformylation of terminal alkynes is catalysed by the zwitterionic rhodium complex, [(cod)Rh+(η6-C6H6BPh3)–](cod = cycloocta-1,5-diene); this highly regio- and stereo-selective reaction affords (Z)-3-germylalk-2-enals in 31–82% yield.
F. Monteil and H. Alper, J. Chem. Soc., Chem. Commun., 1995, 1601 DOI: 10.1039/C39950001601
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