Issue 23, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Control of aggregation through anion encapsulation in clusters of the V/O/RPO32– system: synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][VV4O6F(PhPO3)4] and [NBun4]2[VV3VVIO6F(PhPO3)4]

Qin Chen  and  Jon Zubieta  

Abstract

The reaction of [(NBun4)][V5O7(PhPO3)5(OMe)2] with HBF4·Et2O in acetonitrile yields the tetranuclear vanadium(V) cluster [NBun4][V4O6F(PhPO3)4]1 which upon reduction with organohydrazine yields the mixed-valence cluster [NBun4]2[VV3VIVO6F (PhPO3)4]2.

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Article information

DOI
https://doi.org/10.1039/C39940002663
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2663-2664

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Control of aggregation through anion encapsulation in clusters of the V/O/RPO32– system: synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][VV4O6F(PhPO3)4] and [NBun4]2[VV3VVIO6F(PhPO3)4]

Q. Chen and J. Zubieta, J. Chem. Soc., Chem. Commun., 1994, 2663 DOI: 10.1039/C39940002663

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