Issue 15, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

T-shaped intermolecular CH ⋯π(C[triple bond, length half m-dash]C) interactions in chloroform solvates of gold(I) ethyne complexes

Thomas E. Müller,   D. Michael P. Mingos  and  David J. Williams  

Abstract

The molecular structures of the chloroform solvates of the ethynediyl digold complexes NpPh2P–Au–C[triple bond, length half m-dash]C–Au–PNpPh2·2CHCl31(Np = naphthyl) and Np2PhP–Au–C[triple bond, length half m-dash]C–Au–PNp2Ph·6CHCl32 have been determined by X-ray techniques; although none of the compounds have short Au ⋯ Au contacts compounds 1 and 2 do exhibit novel C–H ⋯π interactions between the protons of CHCl3 molecules and the π-electron system of the C[triple bond, length half m-dash]C bond.

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Article information

DOI
https://doi.org/10.1039/C39940001787
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1787-1788

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T-shaped intermolecular CH ⋯π(C[triple bond, length half m-dash]C) interactions in chloroform solvates of gold(I) ethyne complexes

T. E. Müller, D. M. P. Mingos and D. J. Williams, J. Chem. Soc., Chem. Commun., 1994, 1787 DOI: 10.1039/C39940001787

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