SCHEDULED MAINTENANCE
The reaction of PPh4[VO2Cl2] with PhAsO3H2 in acetonitrile for 36 h at 100 °C and autogenous pressure yields [(V2O3)(Ph6As6O14)], an unusual cluster with a {V2O3}4+ core straddled by the hexadentate ligand {Ph6As6O14}4–, which forms via thermally induced condensation of PhAsO3H2 groups.
J. Salta, Y. Chang and J. Zubieta, J. Chem. Soc., Chem. Commun., 1994, 1039 DOI: 10.1039/C39940001039
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