Issue 6, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Stepwise activation of σ-thienyl ligands at di-tungsten centres

Malcolm H. Chisholm,   Scott T. Haubrich,   James D. Martin  and  William E. Streib  

Abstract

The attachment of σ-2-thienyl and σ-2-benzothienyl ligands (but not σ-3-thiophenyl ligands) to W26+ containing centres leads to the stepwise opening of the five-membered ring to generate, in the presence of tert-butyl alcohol, a novel thiolato-µ-alkylidyne metallocylcle in W2(OBut)5(µ-SC4H3)(η1-2-SC4H3), which has been structurally characterized; the intermediate W2(OBut)4(µ-SC4H3)(η1-2-SC4H3), which contains a bridging thiolato–vinylidene metallocycle has been characterized by NMR spectroscopy.

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Article information

DOI
https://doi.org/10.1039/C39940000683
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 683-684

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Stepwise activation of σ-thienyl ligands at di-tungsten centres

M. H. Chisholm, S. T. Haubrich, J. D. Martin and W. E. Streib, J. Chem. Soc., Chem. Commun., 1994, 683 DOI: 10.1039/C39940000683

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