SCHEDULED MAINTENANCE
4-Bromomethyldimethylsiloxy-2,8,8-trimethyldec-1-en-5,9-diyne 11 is prepared and its radical cyclisation leads to a stereoselective synthesis of a hydrindene framework 13via three consecutive 5-exo-dig, 5-exo-trig and 6-exo-dig radical processes.
M. Journet, E. Lacôte and M. Malacria, J. Chem. Soc., Chem. Commun., 1994, 461 DOI: 10.1039/C39940000461
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