Cationic morpholine lipids 1 and 6 undergo complex phase transition patterns and exhibit metastable phases; lipids 1,2 and 6 become thermotropic liquid crystals through the first phase transition temperatures, whereas 5 and 7 lose birefringence and become opaque solids.
G. Kumaravel, I. I. Negulescu and R. D. Gandour, J. Chem. Soc., Chem. Commun., 1993, 905 DOI: 10.1039/C39930000905
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