The half-sandwich compound [Ru(η5-C5Me5)(dppe)]Cl 1 is shown to coordinate simple inorganic gases viz. H2, Cl2, NO and O2; of these the side-on bonded peroxide [Ru(η2-O2)(η5-C5Me5)(dppe)]+2 is described in more detail including its X-ray crystal structure.
K. Kirchner, K. Mauthner, K. Mereiter and R. Schmid, J. Chem. Soc., Chem. Commun., 1993, 892 DOI: 10.1039/C39930000892
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