Issue 3, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Stabilization of a cobalt(II) phthalocyanine oxidation catalyst by intercalation in a layered double hydroxide host

Malama Chibwe  and  Thomas J. Pinnavaia  

Abstract

Cobalt(II) phthatocyaninetetrasulfonate [Co(pcts)]4– intercalated into a MgsAl2.5-layered double hydroxide (LDH) sxhibited greatly enhanced catalytic stability compared to the homogeneous catalyst for the autoxidation of 2,6-di-tert-butylphenol to the corresponding diphenoquine at 35 ± 2 °C; under homogeneous reaction conditions the Domplex deactivated within 25 catalytic turnovers, whereas the LDH-supported species remained fully active even after nore than 3200 turnovers.

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Article information

DOI
https://doi.org/10.1039/C39930000278
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 278-280

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Stabilization of a cobalt(II) phthalocyanine oxidation catalyst by intercalation in a layered double hydroxide host

M. Chibwe and T. J. Pinnavaia, J. Chem. Soc., Chem. Commun., 1993, 278 DOI: 10.1039/C39930000278

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