Issue 24, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Electrosynthesis of amino acids from a molybdenum nitride via nitrogen–carbon and carbon–carbon bond formation reactions involving imides and nitrogen ylides: X-ray structure of trans-[MoCl(NCHCO2Me)(Ph2PCH2CH2PPh2)2]·CH2Cl2

David L. Hughes,   Saad K. Ibrahim,   Colin J. Macdonald,   Hapipah Mohd. Ali  and  Christopher J. Pickett  

Abstract

Sequential nitrogen–carbon and carbon–carbon bond formation, and an electrochemical Mo–N bond cleavage step, define a pathway to methyl esters of the amino acids glycine and alanine from the molybdenum nitride trans-[MoCl(N)(Ph2PCH2CH2PPh2)2], a key intermediate being the metallo-nitrogen ylide trans-[MoCl(NCHCO2Me)(Ph2PCH2CH2PPh2)2], the structure of which has been determined crystallographically.

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Article information

DOI
https://doi.org/10.1039/C39920001762
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1762-1763

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Electrosynthesis of amino acids from a molybdenum nitride via nitrogen–carbon and carbon–carbon bond formation reactions involving imides and nitrogen ylides: X-ray structure of trans-[MoCl(NCHCO2Me)(Ph2PCH2CH2PPh2)2]·CH2Cl2

D. L. Hughes, S. K. Ibrahim, C. J. Macdonald, H. Mohd. Ali and C. J. Pickett, J. Chem. Soc., Chem. Commun., 1992, 1762 DOI: 10.1039/C39920001762

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