Issue 23, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

Intermolecular C–F and intramolecular C–H activation reaction of [Re(η5-C5Me5)(CO)3] with hexafluorobenzene: crystal and molecular structure of [Re(η6-C5Me4CH2)(CO)2(C6F5)]

A. Hugo Klahn,   Madeleine H. Moore  and  Robin N. Perutz  

Abstract

Photochemical reaction of [Re(η5-C5Me5)(CO)3] with hexafluorobenzene yields [Re(η6-C5Me4CH2)(CO)2(C6F5)] formed by insertion into a C–F bond of C6F6 and concomitant insertion into a methyl C–H bond; the reactions of [Re(η6-C5Me4CH2)(CO)2(C6F5)] with PMe3 and with HCl show that the (η6-C5Me4CH2) ligand is subject to both nucleophilic and electrophilic attack.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39920001699
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1699-1701

Permissions

Request permissions

Intermolecular C–F and intramolecular C–H activation reaction of [Re(η5-C5Me5)(CO)3] with hexafluorobenzene: crystal and molecular structure of [Re(η6-C5Me4CH2)(CO)2(C6F5)]

A. H. Klahn, M. H. Moore and R. N. Perutz, J. Chem. Soc., Chem. Commun., 1992, 1699 DOI: 10.1039/C39920001699

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements