SCHEDULED MAINTENANCE
Tertiary diphosphines form complexes with various metal ring carbonyl cations of new and novel structural types including ring adducts, e.g. [(η4-C7H9-5-exo-η1-PPh2CH2PPh2)Fe(CO)3]BF4 diphosphine bridged ring dimers, e.g. Ph2P(CH2)2PPh2[(η4-C7H9)Fe(CO)3]2[BF4]2 and diphosphine bridged ring-metal dimers, e.g.. [(η5-C5H5)Fe(CO)2PPh2(CH2)3PPh2(exo-η6-C7H7)Cr(CO)3][BF4]2.
D. A. Brown, J. Burns, I. El-Gamati, W. K. Glass, K. Kreddan, M. Salama, D. Cunningham, T. Higgins and P. McArdle, J. Chem. Soc., Chem. Commun., 1992, 701 DOI: 10.1039/C39920000701
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