Issue 2, 1992

Self assembly of isostructural copper(I)-silver(I) butterfly clusters with 2-mercaptothiazoline; syntheses and structures of (PPh3)2Cu4(C3H4NS2)4, [(C5H5N)Cu4(C3H4NS2)4]n, (PPh3)2Ag4(C3H4NS2)4 and (PPh3)2Ag2Cu2(C3H4NS2)4

Abstract

The crystal structures of tetranuclear butterfly clusters of CuI, AgI and the mixed metal AgI2CuI2 compound as obtained by reaction of the metal acetates with 2-mercaptothiazoline, and subsequent treatment of the insoluble polymeric clusters with organic bases are reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 146-148

Self assembly of isostructural copper(I)-silver(I) butterfly clusters with 2-mercaptothiazoline; syntheses and structures of (PPh3)2Cu4(C3H4NS2)4, [(C5H5N)Cu4(C3H4NS2)4]n, (PPh3)2Ag4(C3H4NS2)4 and (PPh3)2Ag2Cu2(C3H4NS2)4

J. P. Fackler, C. A. López, R. J. Staples, S. Wang, R. E. P. Winpenny and R. P. Lattimer, J. Chem. Soc., Chem. Commun., 1992, 146 DOI: 10.1039/C39920000146

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