Issue 21, 1991

A new diphenylantimony oxide containing a planar Sb6O6 ring

Abstract

Treatment of diphenylantimony bromide oxide, (Ph2SbBrO)2, with silver oxalate leads to a novel ionic product, containing a planar twelve-membered cyclic antimony–oxygen dication in which two pairs of adjacent antimony atoms are further linked by hydroxy bridges to give Sb2O2 rings and a quadridentate oxalate is coordinated between the two remaining antimony atoms of the ring; the counter ions are two cis-dioxalatodiphenylantimony anions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1555-1556

A new diphenylantimony oxide containing a planar Sb6O6 ring

I. G. Southerington, M. J. Begley and D. B. Sowerby, J. Chem. Soc., Chem. Commun., 1991, 1555 DOI: 10.1039/C39910001555

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