SCHEDULED MAINTENANCE
Very long-range isotope shifts have been observed in the 500 MHz proton NMR spectra of several deuteriated haemins; these shifts are consistent with a redistribution of delocalised π spin density upon fractional resolution, owing to deuteriation, of the ground state orbital degeneracy of the low-spin iron(III) ion.
C. J. Medforth, F. Shiau, G. N. La Mar and K. M. Smith, J. Chem. Soc., Chem. Commun., 1991, 590 DOI: 10.1039/C39910000590
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