Issue 16, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

Organometallic photochemistry in supercritical fluids: the reaction of H2 with [(η5-C5H5)M(CO)3](M [double bond, length half m-dash] Re and Mn) and the formation of a ‘non-classical’dihydrogen complex of manganese(I)

Steven M. Howdle  and  Martyn Poliakoff  

Abstract

U.v. photolysis of [(cp)M(CO)3](cp =η5-C5H5,M [double bond, length half m-dash] Re and Mn) at room temperature in supercritical Xe pressurized with H2, leads to formation of the dihydride, [(Cp)Re(CO)2H2], and the ‘non-classical’ dihydrogen complex, [(cp)Mn(CO)2(H2)], which is stabilized by the high pressure of H2.

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Article information

DOI
https://doi.org/10.1039/C39890001099
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1099-1101

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Organometallic photochemistry in supercritical fluids: the reaction of H2 with [(η5-C5H5)M(CO)3](M [double bond, length half m-dash] Re and Mn) and the formation of a ‘non-classical’dihydrogen complex of manganese(I)

S. M. Howdle and M. Poliakoff, J. Chem. Soc., Chem. Commun., 1989, 1099 DOI: 10.1039/C39890001099

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