Addition of SCl2, SOCl2, SO2Cl2 or SeCl4 to liquid ammonia followd by Pt(PR3)2Cl2 gives complexes of the type Pt(S2N2)(PR3)2, Pt(NSO)2(PR3)2, Pt[(HN)2SO2](PR3)2, and Pt(Se2N2)(PR3)2 respectively; the X-ray structure of Pt[(HN)2SO2](PPh2Me)2 is reported.
I. P. Parkin, A. M. Z. Slawin, D. J. Williams and J. D. Woollins, J. Chem. Soc., Chem. Commun., 1989, 1060 DOI: 10.1039/C39890001060
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