Issue 12, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of three-vertex metallaboranes from monoborane precursors: X-ray crystal structures of the molybdenum and ruthenium complexes [Mo(η-C5H5)2H(η2-B2H5)] and [Ru(η-C5Me5)(PMe3)(η2-B2H7)]

Peter D. Grebenik,   Malcolm L. H. Green,   Malcolm A. Kelland,   John B. Leach,   Philip Mountford,   Graham Stringer,   Neil M. Walker  and  Luet-Lok Wong  

Abstract

The novel three-vertex metallaborane [Ru(η–C5Me5)(PMe3)(η2-B2H7)](1) has been synthesised by reaction of [Ru(η-C5Me5)(PMe3)Cl2] with NaBH4; homologation is also observed in the reaction of [Mo(η-C5H5)2H2] with BH3·THF, which forms [Mo(η-C5H5)2H(η2-B2H5)](2); X-ray crystal structures of compounds (1) and (2) are reported.

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Article information

DOI
https://doi.org/10.1039/C39880000799
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 799-801

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Formation of three-vertex metallaboranes from monoborane precursors: X-ray crystal structures of the molybdenum and ruthenium complexes [Mo(η-C5H5)2H(η2-B2H5)] and [Ru(η-C5Me5)(PMe3)(η2-B2H7)]

P. D. Grebenik, M. L. H. Green, M. A. Kelland, J. B. Leach, P. Mountford, G. Stringer, N. M. Walker and L. Wong, J. Chem. Soc., Chem. Commun., 1988, 799 DOI: 10.1039/C39880000799

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