Issue 20, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Phosphorus double functionalisation by template condensations; formation of P–C and P–O bonds from metallocycles. Synthesis and crystal structure of cis-[PdCl2{Ph2PCHC(Ph)OP(Ph)(o-C6H4CH2NMe2H}]Cl

Pierre Braunstein,   Dominique Matt,   Dominique Nobel  and  Jean Fischer  

Abstract

The air-stable bis-chelate complexes cis-[[graphic omitted])Ph}2](1) and [(L)[graphic omitted])Ph}][(3), (LH)= dimethylbenzylamine; (5), (LH)= 8-methylquinoline] react smoothly with 1 equiv. of PhPCl2 to afford coupling products [(2), and (4) and (6), respectively], involving the O atom of the enolate ligand and the Pd-bound C atom of the cyclometallated ligand.

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Article information

DOI
https://doi.org/10.1039/C39870001530
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1530-1532

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Phosphorus double functionalisation by template condensations; formation of P–C and P–O bonds from metallocycles. Synthesis and crystal structure of cis-[PdCl2{Ph2PCHC(Ph)OP(Ph)(o-C6H4CH2NMe2H}]Cl

P. Braunstein, D. Matt, D. Nobel and J. Fischer, J. Chem. Soc., Chem. Commun., 1987, 1530 DOI: 10.1039/C39870001530

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