SCHEDULED MAINTENANCE
Epoxidation of alkenes and hydroxylation of alkanes by dioxygen and Zn as a reducing agent, with good yields (up to 50%) based on Zn and rates (up to 200 turnovers of the catalyst per hour), were achieved by using manganese porphyrin catalysts in the presence of 1-methylimidazole and acetic acid.
P. Battioni, J. F. Bartoli, P. Leduc, M. Fontecave and D. Mansuy, J. Chem. Soc., Chem. Commun., 1987, 791 DOI: 10.1039/C39870000791
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