The phosphoryl transfer reactions of adenosine 5′-[α,β-18O]diphosphate trianion in acetonitrile, acetonitrile–t-butyl alcohol, and neat t-butyl alcohol are all accompained by closely similar bridge-to-non-bridge scrambling in the reisolated starting material; the simplest interpretation involves a monomeric metaphosphate intermediate even in the presence of hydroxylic solvent.
P. M. Cullis and D. Nicholls, J. Chem. Soc., Chem. Commun., 1987, 783 DOI: 10.1039/C39870000783
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