Reactions between iodide or cationic derivatives of cyclopalladated complexes and alkynes lead to the synthesis of heterocyclic compounds through insertion of one or two alkynes into the Pd–C bonds, the new N–C bonds being formed via reductive elimination of palladium(0).
F. Maassarani, M. Pfeffer and G. Le Borgne, J. Chem. Soc., Chem. Commun., 1987, 565 DOI: 10.1039/C39870000565
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