Issue 7, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of a new bifunctional hemilabile ligand by insertion of PhNCO into a co-ordinated β-phosphinoketonate. Crystal structure of [(o-C6H4CH2NMe2)Pd(Ph2PC[C(O)NHPh][C(Ph)O])]

Salah-Eddine Bouaoud,   Pierre Braunstein,   Daniel Grandjean,   Dominique Matt  and  Dominique Nobel  

Abstract

The air-stable complex [(o-[graphic omitted])Ph}](1) is an ambident reactive species which readily reacts with PhNCO affording the two isomers (2a)(title complex) and (2b) which formally result from insertion of isocyanate into the C-H bond of the phosphinoketonate; the resulting bifunctional phosphine ligand displays hemilabile character.

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Article information

DOI
https://doi.org/10.1039/C39870000488
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 488-490

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Synthesis of a new bifunctional hemilabile ligand by insertion of PhNCO into a co-ordinated β-phosphinoketonate. Crystal structure of [(o-C6H4CH2NMe2)Pd(Ph2PC[C(O)NHPh][C(Ph)O])]

S. Bouaoud, P. Braunstein, D. Grandjean, D. Matt and D. Nobel, J. Chem. Soc., Chem. Commun., 1987, 488 DOI: 10.1039/C39870000488

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