Issue 18, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Enantioselective photoreactions of tropolone alkyl ethers in a crystalline inclusion complex with optically active 1,6-di(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol

Fumio Toda  and  Koichi Tanaka  

Abstract

Irradiation of complexes of tropolone alkyl ethers with optically active 1,6-di(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol in the crystalline state gave the [2 + 2] photoreaction product, 1-alkoxybicyclo[3.2.0]hepta-3,6-dien-2-one, and its ring-opened derivative, alkyl 4-oxocyclopent-2-ene-1-acetate, in 100 and 72–91% enantiomeric excess.

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Article information

DOI
https://doi.org/10.1039/C39860001429
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1429-1430

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Enantioselective photoreactions of tropolone alkyl ethers in a crystalline inclusion complex with optically active 1,6-di(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol

F. Toda and K. Tanaka, J. Chem. Soc., Chem. Commun., 1986, 1429 DOI: 10.1039/C39860001429

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