Issue 10, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Methylene, oxygen, and sulphur addition to a µ-alkylidyne ligand in an iron–molybdenum complex: X-ray crystal structures of [FeMo{µ-σ,η-C(C6H4Me-4)[double bond, length half m-dash]CH2}(µ-CH2)(CO)5(η-C5H5)], [FeMo{µ-η3-C(C6H4Me-4)C(OMe)C(H)}(CO)5(η-C5H5)], and [FeMo{µ-η-SC(C6H4Me-4)}(CO)5(η-C5H5)]

M. Esther Garcia,   John C. Jeffery,   Paul Sherwood  and  F. Gordon A. Stone  

Abstract

The compound [FeMo(µ-CC6H4Me-4)(CO)6(η-C5H5)] is a verstile reagent for studying the reactivity of an alkylidyne ligend bridging a heteronuclear metal-metal bond, as shown by its reactions with diazomethane, oxygen, and sulphur.

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Article information

DOI
https://doi.org/10.1039/C39860000802
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 802-804

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Methylene, oxygen, and sulphur addition to a µ-alkylidyne ligand in an iron–molybdenum complex: X-ray crystal structures of [FeMo{µ-σ,η-C(C6H4Me-4)[double bond, length half m-dash]CH2}(µ-CH2)(CO)5(η-C5H5)], [FeMo{µ-η3-C(C6H4Me-4)C(OMe)C(H)}(CO)5(η-C5H5)], and [FeMo{µ-η-SC(C6H4Me-4)}(CO)5(η-C5H5)]

M. E. Garcia, J. C. Jeffery, P. Sherwood and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1986, 802 DOI: 10.1039/C39860000802

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