Issue 6, 1986

Upon the electronic structure of the µ-oxo-bis[pentachlororuthenate(IV)] anion and the non-existence of caesium µ-oxo-bis[pentabromoruthenate(IV)]

Abstract

The electronic absorption spectrum of [Ru2OCl10]4– in a room-temperature ionic liquid shows three discrete bands in the near-i.r. region due to electronic transitions associated with the π(Ru–O-Ru) skeleton; claims of the synthesis of Cs4[Ru2OBr10] have been demonstrated to be in error (the reported products being mixtures of Cs3[Ru2Br9] and CsBr), and the detailed structure of [Ru2Br9]3–[r(RuRu)= 0.287 nm] is reported for the first time.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 483-485

Upon the electronic structure of the µ-oxo-bis[pentachlororuthenate(IV)] anion and the non-existence of caesium µ-oxo-bis[pentabromoruthenate(IV)]

D. Appleby, R. I. Crisp, P. B. Hitchcock, C. L. Hussey, T. A. Ryan, J. R. Sanders, K. R. Seddon, J. E. Turp and J. A. Zora, J. Chem. Soc., Chem. Commun., 1986, 483 DOI: 10.1039/C39860000483

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