Issue 1, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Ethylene insertion into the W–C bond of the η2-formaldehyde ligand system of W(PMe3)4(η2-CH2O)H2 giving the oxometallacyclopentane derivative W(OCH2CH2CH2)(PMe3)2(C2H4)2 and related studies

Malcolm L. H. Green  and  Gerard Parkin  

Abstract

The η2-formaldehyde compound W(PMe3)4(η2-CH2O)H2 reacts with ethylene to give initially the unstable oxometallacycle [graphic omitted]H2)(PMe3)2(C2H4)2; with propene W(PMe3)4(CO)H2 is formed and with butadiene the product is W(PMe3)3(η-C4H6)(η2-CH2O).

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39860000090
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 90-91

Permissions

Request permissions

Ethylene insertion into the W–C bond of the η2-formaldehyde ligand system of W(PMe3)4(η2-CH2O)H2 giving the oxometallacyclopentane derivative W(OCH2CH2CH2)(PMe3)2(C2H4)2 and related studies

M. L. H. Green and G. Parkin, J. Chem. Soc., Chem. Commun., 1986, 90 DOI: 10.1039/C39860000090

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements