Issue 1, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation of metallacyclosulphones of nickel, palladium, and platinum and the X-ray crystal structure of trans-2,4-diphenyl-1,1-bis(triphenylarsine)platinathietane-3,3-dioxide

Kwok W. Chiu,   John Fawcett,   William Henderson,   Raymond D. W. Kemmitt  and  David R. Russell  

Abstract

A variety of metallathietane-3,3-dioxides of platinum(II), palladium(II), and nickel(II), [[graphic omitted]HPh}L2] are formed in high yield by the action of the dianion [PhCHS(O)2CHPh]2– upon either cis- or trans-[MCl2L2]; the X-ray structure of the title compound (1a) establishes the presence of a puckered platinathietane-3,3-dioxide ring with no substantial Pt ⋯ S transannular bonding.

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Article information

DOI
https://doi.org/10.1039/C39860000041
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 41-42

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Preparation of metallacyclosulphones of nickel, palladium, and platinum and the X-ray crystal structure of trans-2,4-diphenyl-1,1-bis(triphenylarsine)platinathietane-3,3-dioxide

K. W. Chiu, J. Fawcett, W. Henderson, R. D. W. Kemmitt and D. R. Russell, J. Chem. Soc., Chem. Commun., 1986, 41 DOI: 10.1039/C39860000041

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