Issue 22, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of new cadmium alkyls by cocodensation of cadmium vapour with trifluorosilyl and trifluoromethyl radicals

M. A. Guerra,   T. R. Bierschenk  and  R. J. Lagow  

Abstract

The very reactive new compounds (Cd)(SiF3)2 and Cd(CF3)2 have been prepared by cocondensation of cadmium vapour with triflurosilyl and triflucromethyl radicals, 19F n.m.r. spectroscopy showing that Cd(SiF3)2 slowly decomposes at room temperature while Cd(CF3)2 decomposes at +5 °C; the addition of glyme (1,2-dimethoxyethane) at low temperature allowed Cd(SiF3)2· glyme and Cd(CF3)2· glyme to be isolated at room temperature.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39850001550
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1550-1551

Permissions

Request permissions

Synthesis of new cadmium alkyls by cocodensation of cadmium vapour with trifluorosilyl and trifluoromethyl radicals

M. A. Guerra, T. R. Bierschenk and R. J. Lagow, J. Chem. Soc., Chem. Commun., 1985, 1550 DOI: 10.1039/C39850001550

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements