Issue 21, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Transition metal–hydrogen–alkali metal bonds: syntheses and structures of W(PMe3)3H5Na(15-crown-5), W(PMe3)3H5K(18-crown-6), and [W(PMe3)3H5Li]4

Judith A. Bandy,   Adam Berry,   Malcolm L. H. Green  and  Keith Prout  

Abstract

Treatment of W(PMe3)3H6 with BunLi, NaH, or KH gives W(PMe3)3H5M, M = Li, Na, or, with the appropriate crown ethers W(PMe3)3H5Na(15-crown-5) and W(PMe3)3H5(18-crown-6): the crystal structure of the crown ether compounds of sodium and potassium and of [W(PMe3)3H5Li]4 have been determined.

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Article information

DOI
https://doi.org/10.1039/C39850001462
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1462-1464

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Transition metal–hydrogen–alkali metal bonds: syntheses and structures of W(PMe3)3H5Na(15-crown-5), W(PMe3)3H5K(18-crown-6), and [W(PMe3)3H5Li]4

J. A. Bandy, A. Berry, M. L. H. Green and K. Prout, J. Chem. Soc., Chem. Commun., 1985, 1462 DOI: 10.1039/C39850001462

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