Issue 10, 1985

On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

Abstract

Competition experiments with various dithiocarbonates show that the deoxygenation occurs by addition of stannyl radicals to give (2) followed by fragmentation rather than by direct SH2 attack on sulphide sulphur.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 646-647

On the mechanism of reduction of dithiocarbonates (xanthates) with tributylstannane

D. H. R. Barton, D. Crich, A. Löbberding and S. Z. Zard, J. Chem. Soc., Chem. Commun., 1985, 646 DOI: 10.1039/C39850000646

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