Issue 9, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

The unusual bioctahedral dirhenium(II,III) complex [Re2(µ-Cl)(µ-C[double bond, length half m-dash]NHBut)(µ-dppm)2Cl2(CNBut)2]PF6[dppm = bis(diphenylphosphino)methane]: a product of the non-cleavage reaction between Re2Cl4(dppm)2 and t-butyl isocyanide

Timothy J. Barder,   Douglas Powell  and  Richard A. Walton  

Abstract

A product from the reaction of the triply bonded complex Re2Cl4(dppm)2[dppm = bis(diphenylphosphino)methane] with two equivalents of t-butyl isocyanide is the novel paramagnetic µ-iminyl dirhenium(II,III) complex [Re2(µ-Cl)(µ-C[double bond, length half m-dash]NHBut)(µ-dppm)2Cl2(CNBut)2]PF6, a species which is different structurally from the complex [Re2Cl3(dppm)2(CNBut)3]PF6 which is formed when three equivalents of isocyanide ligand are used.

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Article information

DOI
https://doi.org/10.1039/C39850000550
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 550-551

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The unusual bioctahedral dirhenium(II,III) complex [Re2(µ-Cl)(µ-C[double bond, length half m-dash]NHBut)(µ-dppm)2Cl2(CNBut)2]PF6[dppm = bis(diphenylphosphino)methane]: a product of the non-cleavage reaction between Re2Cl4(dppm)2 and t-butyl isocyanide

T. J. Barder, D. Powell and R. A. Walton, J. Chem. Soc., Chem. Commun., 1985, 550 DOI: 10.1039/C39850000550

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