Issue 20, 1984

Selective palladium catalysed monohydroesterification of diols

Abstract

Olefins react with diols (e.g. ethylene glycol) under oxidative carbonylation and acidic conditions, using palladium and copper (II) chloride as catalysts, to give hydroxy esters in good yields; this mild reaction (room temperature, 1 atm) is a regioselective one.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1349-1351

Selective palladium catalysed monohydroesterification of diols

S. B. Fergusson and H. Alper, J. Chem. Soc., Chem. Commun., 1984, 1349 DOI: 10.1039/C39840001349

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